Remarks on preparation of indandione detection reagents

A modified Claisen condensation with sliced sodium at a higher temperature was recommended for the production of ungranulated charcoal. A new ninhydrin production method by oxidation of benzaldiketohydrinden using available reagents was tried and was unsuccessful. Triketohydrinden was obtained by boiling ninhydrin in acetic acid anhydrides

monotonic and low cycle fatigue properties of earthquake damaged new zealand steel reinforcing bars the experience after the christchurch 2010 2011 earthquakes

Abstract The 2010 and 2011 Christchurch seismic events have highlighted the limitations of the current knowledge in assessing the residual capacity of earthquake-damaged reinforced concrete (RC) buildings. An important challenge during the assessment phase was determining the residual ductility and the remaining low-cycle fatigue life of damaged rebars. Low-cycle fatigue is a possible failure mechanism of steel reinforcing bars when subjected to large-amplitude cyclic loads, such as due to earthquakes. While a single seismic event may not cause rebar failure, the low-cycle fatigue life will be reduced due to plastic strain. Also, New Zealand (NZ)-manufactured Grade 300E is prone to strain ageing. This phenomenon causes a change in mechanical properties, such as increase in yield and ultimate tensile strength, return of a discontinuous yield point, reduction in ductility and rise in the ductile/brittle transition temperature, and must be considered in damage assessment. This paper discusses the effects of strain ageing on the monotonic and cyclic steel mechanical properties. Low-cycle fatigue tests were conducted on Grade 300E steel rebars. Reinforcing bar samples were subjected to constant and fully-reversed strain amplitude cycles. Strain amplitudes ranged from 0.5% to 3%. The strain-fatigue life curve for the un-aged steel was determined. The strain ageing effects on the fatigue life of Grade 300E were then investigated. Specimens were cyclically tested up to the 33% and 66% fatigue life previously determined and "artificially" aged at 100°C. Finally, they were cyclically tested until failure. The experimental data were analyzed and low-cycle fatigue models were calibrated using the Coffin-Manson empirical relationship. Fatigue lives of the un-aged and aged samples were then compared. Preliminary observations suggested that strain-ageing triggers a premature crack initiation which propagates until failure

Graphs with bounded tree-width and large odd-girth are almost bipartite

We prove that for every $k$ and every $\varepsilon>0$, there exists $g$ such that every graph with tree-width at most $k$ and odd-girth at least $g$ has circular chromatic number at most $2+\varepsilon$

Navigating International, Interdisciplinary, and Indigenous Collaborative Inquiry

This report describes how multiple community constituents came together with university researchers to develop a shared agenda for studying young indigenous people in five international circumpolar communities. The paper focuses on the setup and process of an initial face-to-face methodological planning workshop involving youth and adult community members and academics. Members of Yup’ik, Inupiat, Eveny, Inuit, and Sámi communities from Siberia to Norway participated in the workshop and engaged in negotiations to arrive at shared research interests. This was essential since the ultimate goal of the research is translational and transformative, spurring social action in communities. Describing the beginning stage of this project and the underlying participatory methodology offers insight into how the approach engaged community members with varying degrees of sustained interest and practical success. It, therefore, articulates a methodological approach for international community-based participatory research

Search for weakly interacting sub-eV particles with the OSQAR laser-based experiment: results and perspectives

Recent theoretical and experimental studies highlight the possibility of new fundamental particle physics beyond the Standard Model that can be probed by sub-eV energy experiments. The OSQAR photon regeneration experiment looks for "Light Shining through a Wall" (LSW) from the quantum oscillation of optical photons into "Weakly Interacting Sub-eV Particles" (WISPs), like axion or axion-like particles (ALPs), in a 9 T transverse magnetic field over the unprecedented length of $2 \times 14.3$ m. No excess of events has been detected over the background. The di-photon couplings of possible new light scalar and pseudo-scalar particles can be constrained in the massless limit to be less than $8.0\times10^{-8}$ GeV$^{-1}$. These results are very close to the most stringent laboratory constraints obtained for the coupling of ALPs to two photons. Plans for further improving the sensitivity of the OSQAR experiment are presented.Comment: 7 pages, 7 figure

Exozodiacal clouds: hot and warm dust around main sequence stars

peer reviewedA warm/hot dust component (at temperature $>$ 300K) has been detected around $\sim$ 20% of stars. This component is called "exozodiacal dust" as it presents similarities with the zodiacal dust detected in our Solar System, even though its physical properties and spatial distribution can be significantly different. Understanding the origin and evolution of this dust is of crucial importance, not only because its presence could hamper future detections of Earth-like planets in their habitable zones, but also because it can provide invaluable information about the inner regions of planetary systems. In this review, we present a detailed overview of the observational techniques used in the detection and characterisation of exozodiacal dust clouds ("exozodis") and the results they have yielded so far, in particular regarding the incidence rate of exozodis as a function of crucial parameters such as stellar type and age, or the presence of an outer cold debris disc. We also present the important constraints that have been obtained, on dust size distribution and spatial location, by using state-of-the-art radiation transfer models on some of these systems. Finally, we investigate the crucial issue of how to explain the presence of exozodiacal dust around so many stars (regardless of their ages) despite the fact that such dust so close to its host star should disappear rapidly due to the coupled effect of collisions and stellar radiation pressure. Several potential mechanisms have been proposed to solve this paradox and are reviewed in detail in this paper. The review finishes by presenting the future of this growing field

Optical Holonomic Quantum Computer

In this paper the idea of holonomic quantum computation is realized within quantum optics. In a non-linear Kerr medium the degenerate states of laser beams are interpreted as qubits. Displacing devices, squeezing devices and interferometers provide the classical control parameter space where the adiabatic loops are performed. This results into logical gates acting on the states of the combined degenerate subspaces of the lasers, producing any one qubit rotations and interactions between any two qubits. Issues such as universality, complexity and scalability are addressed and several steps are taken towards the physical implementation of this model.Comment: 16 pages, 3 figures, REVTE

Unraveling the Mystery of Exozodiacal Dust

Exozodiacal dust clouds are thought to be the extrasolar analogs of the Solar System's zodiacal dust. Studying these systems provides insights in the architecture of the innermost regions of planetary systems, including the Habitable Zone. Furthermore, the mere presence of the dust may result in major obstacles for direct imaging of earth-like planets. Our EXOZODI project aims to detect and study exozodiacal dust and to explain its origin. We are carrying out the first large, near-infrared interferometric survey in the northern (CHARA/FLUOR) and southern (VLTI/PIONIER) hemispheres. Preliminary results suggest a detection rate of up to 30% around A to K type stars and interesting trends with spectral type and age. We focus here on presenting the observational work carried out by our tea